2. Kinetic diagram. Instantaneous" distribution of degrees of polymerization
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2.1.1 Usual assumptions and approximations
We will restrict ourselves to monomers with a single carbon-carbon double bond reactive in free-radical polymerization. The most general typical kinetic scheme involves seven types of chemical processes: initiation, propagation, depropagation, termination, intermolecular transfers, intramolecular transfer/migration and β-scission (Table
2
). The...
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Kinetic diagram. Instantaneous" distribution of degrees of polymerization
Bibliography
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(1) - PLADIS (P.), MEIMAROGLOU (D.), KIPARISSIDES, (C.) -
Prediction of the viscoelastic behavior of low-density polyethylene produced in high-pressure tubular reactors.
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Macromol. React. Eng., 9, p. 271-284 (2015).
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(2) - BROOKS...
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