3. Synthesis and post-synthesis treatments
Historical overview [20]From 1845 onwards, numerous researchers attempted to reproduce the synthesis of natural zeolites: chabazite (CHA), erionite (ERI), mordenite (MOR), clinoptilolite (HEU) and others. These zeolites, formed very slowly (over several hundred or thousand years) by the low-temperature reaction of volcanic ash with alkaline groundwater, are contaminated by metal compounds, quartz or other zeolites, making them difficult to use industrially. First success in the 1940s: Barrer synthesized chabazite (CHA) by reacting leucite (KAlSi2O6) and analcime (NaAlSi2O6) with aqueous solutions of barium chloride at 180-270°C for 2-6 days. In 1948, he succeeded in synthesizing mordenite...
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Synthesis and post-synthesis treatments