Definitions
Heating enthalpy of solids

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K430 V2 Article

Definitions
Heating enthalpy of solids

Author : Robert CASTANET

Publication date: June 10, 1991 | Lire en français

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1. Definitions

1.1 Thermal capacities

When a quantity of heat ΔQ is received by a system and causes a temperature change ΔT = T1 – T2 (with T1 and T2 , respectively the start and end temperatures of heating), the average heat capacity C of the system of mass m is written :

C = ΔQ /ΔT

provided the system undergoes neither reaction nor first-order transition in the Ehrenfest sense (enthalpy and entropy discontinuities) between T1 and T2 , i.e. heat exchanges with the outside have the exclusive effect of raising the temperature of the system (neither heat of reaction nor enthalpy of change of state).

The limiting value of C when ΔT tends towards zero is...

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