Self-healing supramolecular polymers : Supramolecular polymers with π-π interactions

Supramolecular polymers with π-π interactions
Self-healing supramolecular polymers

Author : David PRORIOL

Publication date: January 10, 2017 | Lire en français

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3. Supramolecular polymers with π-π interactions

3.1 First self-repairing supramolecular polymer with π-π interactions

Colquhoun, Hayes et al. described back in 2009 one of the first repairable supramolecular systems based on π-π donor-acceptor interactions (π-stacking). This system comprises a low-molecular-weight polydiimide FPA-1 (table 1) containing numerous electron-deficient sites. This polydiimide is able to fold around the electron-rich sites of the pyrenes located at the end of the LPD-1 PDMS chain (table...

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Supramolecular polymers with π-π interactions