3. Stress corrosion degradation of stainless steels in polluted
environments in PWR reactors
Austenitic stainless steels are highly resistant to stress corrosion
in the primary environment of nominal PWRs, where they crack only
under very specific conditions, either when they are highly work-hardened
and subjected to very severe mechanical stress, or when they have
undergone significant irradiation
[BN 3 755]
.
On the other hand, the presence of oxygen and/or impurities, of
which chlorides are the most dangerous, can lead to cracking of austenitic
stainless steels: experience in boiling water reactors (BWR) has shown
that the presence of dissolved oxygen is sufficient to cause stress
cracking of sensitized or highly work-hardened stainless steels. The
additional presence of chlorides (and possibly sulfates) can lead
to transgranular cracking, even in the absence of sensitization....
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Stress corrosion degradation of stainless steels in polluted environments in PWR reactors