Thermodynamics of polymer solutions
Polymers in solution

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A3050 V2 Article

Thermodynamics of polymer solutions
Polymers in solution

Authors : Patrick PERRIN, Dominique HOURDET

Publication date: January 10, 1997 | Lire en français

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1. Thermodynamics of polymer solutions

1.1 Concentrated solutions

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1.1.1 Flory-Huggins network

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1.1.1.1 Concept

Unlike mixtures of small molecules, polymer solutions show a clear deviation from ideality (Raoult's law), the greater the molar mass of the polymer. This unusual behavior was the first...

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