CALPHAD modeling of multiconstituent diagrams
Equilibrium diagrams

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M4105 V1 Article

CALPHAD modeling of multiconstituent diagrams
Equilibrium diagrams

Author : Jean HERTZ

Publication date: December 10, 2003 | Lire en français

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7. CALPHAD modeling of multiconstituent diagrams

7.1 General methodology

The reader is referred to paragraph 2 of article [M 70] : the thermodynamic equilibrium of a physico-chemical system placed under isobaric-isothermal conditions is achieved when the chemical potentials of all constituents i, j... c are equal in all coexisting phases ϕ, ψ,... (relation (15) of article [M 70] ): μiφ=μiψ,    ∀i,    ∀φ,    ∀ψ

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