1. Approach to intergranular diffusion
In metals, the diffusion of any element except hydrogen is generally much faster at grain boundaries than in the bulk of the crystal. The theoretical underpinnings of this phenomenon can be found, in particular, in a number of books and review articles [M 55]
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Approach to intergranular diffusion
Bibliography
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(1) - PHILIBERT (J.) - Diffusion et Transport de Matière dans les Solides. - Les Éditions de Physique, 472 p. (1985).
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(2) - BALLUFFI (R.W.) - Grain boundary diffusion mechanisms in metals. - Metallurgical Transactions, 13A, p. 2069-2095 (1982).
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