5. Surface energy of liquid alloys – Thermodynamic models
The surface energy of a metal A can be modified by a metallic solute B if this solute adsorbs onto the surface of A. If the surface is represented by an atomic monolayer, adsorption is quantified by the enrichment coefficientY
B
/X
B
, equal to the ratio between the molar fractions of B in the monolayer (Y
B
) and inside the liquid (X
B
) (with Y
A
+Y
B
= X
A
+X
B
= 1). This coefficient, along with the surface energy of the binary alloy AB, can be calculated using the regular solution model describing atomic interactions in the liquid...
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Surface energy of liquid alloys – Thermodynamic models