Potentiometry is an analytical method that links a measurement of electrode potential to the activity of a species in solution. The corresponding electrode is called an indicator electrode.
The indicator electrode (of potential E
ind
), chosen according to the nature of the solute to be determined, is included in a galvanic chain comprising a reference electrode (of potential E
ref
) and one or two electrolytes. Depending on whether there are one or two electrolytes, the potentiometric chain can be written :
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(1) - CONWAY (B.E.) -
Ionic interactions and activity behavior of electrolyte solutions (Interactions ioniques et activité dans les solutions d'électrolyte).
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Chap. 2, p. 111-222. Dans CONWAY (B.E.), BOCKRIS (J.O'M.) et YEAGER (E.). – Comprehensive treatise of electrochemistry (Traité complet d'électrochimie)....
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