Potentiometry is an analytical method that links a measurement of electrode potential to the activity of a species in solution. The corresponding electrode is called an indicator electrode.
The indicator electrode (of potential Eind), chosen according to the nature of the solute to be determined, is included in a galvanic chain comprising a reference electrode (of potential Eref ) and one or two electrolytes. Depending on whether there are one or two electrolytes, the potentiometric chain can be written :
or
The...
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(1) - CONWAY (B.E.) - Ionic interactions and activity behavior of electrolyte solutions (Interactions ioniques et activité dans les solutions d'électrolyte). - Chap. 2, p. 111-222. Dans CONWAY (B.E.), BOCKRIS (J.O'M.) et YEAGER (E.). – Comprehensive treatise of electrochemistry (Traité complet d'électrochimie). Plenum Press, New York,...
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