1. General modeling considerations
In view of its particular practical importance, the following section focuses solely on the case of liquid-vapor phase change (evaporation-condensation), while liquid-solid phase change, which is less studied in comparison (although it is involved in many applications: snow melting, metallurgy/foundry, etc.), is not addressed. Let us simply point out that solidification of a multiconstituent mixture involves two mechanisms, dominated by possible instabilities at the fluid/solid interface:
columnar growth from the cooling surface, leading to the presence of a porous medium ("mushy zone");
growth of equiaxed grains in the cooling liquid solution.
Porous media" models have therefore been developed.
Readers interested in these issues will find some bibliographical...
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General modeling considerations