5. Carbonylation of halides
An alkyl chloroacetate is carbonylated very selectively in excellent yield (98%) to malonate using a cobalt-based catalyst between 60 and 80 ˚C under a pressure of 5 to 25 bar .
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Carbonylation of halides
References
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(1) - AMIEL (J.) dans P. Pascal - Nouveau traité de chimie minérale - . vol. 8, Mason, Paris 1968, p. 542.
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(2) - - Fiche INRS N° 47 1996 (Institut National de Recherche pour la Sécurité) le monoxyde de carbone.
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(3) - FORG (W.) - Linde Ber. Ech. Wiss....
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