1. Liquid-solid transition under pressure
1.1 Simon equation
The first step is to find out how the liquid-solid transition evolves under high pressure. With the exception of a few well-known substances (water, some salts, bismuth, antimony...), the melting temperature of a solid increases with pressure. The empirical relationship :
with :
- Pm and Tm :
- melting pressure and temperature
- a, b and c :
- adjustable constants,
was proposed by Simon
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Liquid-solid transition under pressure
Equations of state for solids under high compression
References
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