18. Glossary
transition vitreuse; glass transition
Temperature at which an undercooled liquid becomes rigid. It is manifested by a specific heat jump in calorimetry and a viscosity of the order of 10
13
Po.
DSC (Differential Scanning Calorimetry)
Common calorimetric technique for locating thermal events and the energies involved.
relaxation : relaxation
A type of molecular mobility involving thermal activation to overcome an energy barrier, as opposed to vibration.
Arrhenius law
Law describing the temperature-dependent evolution of a relaxation process or viscosity, when the energy barrier E does not vary with temperature (equation
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