11. Possible link between dynamics and thermodynamics
A link between the dynamic behavior and thermodynamic characteristics of glass-forming liquids emerges from what has been described above.
Strong liquids have an Arrhenian dynamic behavior and exhibit a small value of ΔC
p
at T
g
.
Brittle liquids have a very super-arrhenic dynamic behavior and generally exhibit a large value of ΔC
p
at T
g
.
For these fragile compounds, the Kauzmann temperature T
K
is usually close to...
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Possible link between dynamics and thermodynamics
Bibliography
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(1) - HILFIKER (R.) -
Polymorphism : In the Pharmaceutical Industry
-
. John Wiley & Sons (2006).
-
(2) - MASSEY (B.S.), WARD-SMITH (J.) -
Mechanics of Fluids, Seventh Edition
-
. Taylor &...
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