Reactions of organic synthesis in ionic liquids : Reactivity in ionic media

Reactivity in ionic media
Reactions of organic synthesis in ionic liquids

Authors : Max Malacria, Jean-Philippe Goddard, Cyril Ollivier, Jean-Christophe PLAQUEVENT, Yves GÉNISSON, Frédéric GUILLEN

Publication date: November 10, 2008 | Lire en français

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3. Reactivity in ionic media

3.1 General principles

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3.1.1 Impact of the ionic environment and the "innocence" of cations and anions

Intuitively, it's easy to foresee that most reaction courses are affected, sometimes dramatically, by the transfer of a molecular solvent to an ionic medium. Classically, chemical reactivity in solution is dependent on solvent interactions with substrates, intermediates and transition states. In the case of conventional solvents, the overriding factor is generally polarity. For ionic solvents, this is high, and is...

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Reactivity in ionic media