Applications
Organic Synthesis under High Pressure

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CHV1610 V2 Article

Applications
Organic Synthesis under High Pressure

Authors : Isabelle CHATAIGNER, Jacques MADDALUNO

Review date: January 11, 2023 | Lire en français

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4. Applications

We present some of the most classic and recent examples of reactions in which pressure exerts an important influence. These examples, which are purely academic, have not yet seen any industrial development. As we do not aim to be exhaustive, we refer the reader to specialized articles covering the relevant field in greater detail.

4.1 Pericyclic reactions

Pericyclic reactions, and cycloadditions in particular, are probably the most extensively studied reactions under pressure. Indeed, they generally have a very negative activation volume (figure

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