Production of boron and sodium perborate
Boron

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J6170 V1 Article

Production of boron and sodium perborate
Boron

Authors : Pierre BLAZY, El-Aïd JDID

Publication date: June 10, 2011 | Lire en français

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5. Production of boron and sodium perborate

5.1 Obtaining basic boron

Elemental boron is obtained by hot reduction of B2O3 obtained :

  • from boric acid by a highly reducing metal (Mg, Ca, alkali, Al);

  • by igneous electrolysis at 1,100°C of B2O3 and/or borates in a molten bath composed of various magnesium salts (MgCl2 , MgSO4 , MgCO3). There is in fact a reduction of the anhydride B2O3 or borates by the magnesium released by electrolysis. The resulting elemental boron contains metal salts and borides, which are removed by boiling in acidic media (HCl, H2SO4) and then optionally by melting with B2O3 and heating under vacuum. The result is elemental boron...

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