Cells for chlorine-sodium electrolysis : Electrolysis voltage

Electrolysis voltage
Cells for chlorine-sodium electrolysis

Author : Jean-Christophe MILLET

Publication date: June 10, 2008 | Lire en français

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3. Electrolysis voltage

For a theoretical calculation of absolute electrode voltage using Nernst's law, see [27] . Using the example of figure , with the reaction :

{Cl}_{2} + 2 e^{-} \to 2 {Cl}^{-}

Nernst's law is written :

π = π_{0} ({Cl}_{2} / {Cl}^{-}) + \frac{R T}{n F} ln \frac{f_{{Cl}_{2}}}{a_{{Cl}^{-}}}

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Electrolysis voltage

(1) - BOCKRIS (J.O'M.) et coll - Comprehensive treatise of electrochemistry. - Plenum Press (1982).
(2) - STORCK (A.), CŒURET (F.) - Éléments de génie électrochimiques. - Lavoisier (1984).
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