Concentration and supersaturation
Crystallization

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J2710 V2 Quizzed article

Concentration and supersaturation
Crystallization

Authors : François PUEL, Stéphane VEESLER, Denis MANGIN

Review date: December 7, 2020 | Lire en français

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1. Concentration and supersaturation

1.1 Concentration units and activity in solution

To express solute content, we use the classic definitions of concentrationC, mass fraction (sometimes expressed in g/100 g solution) and mole fraction.

For electrolyte solutions, it is not always sufficient to use concentrations, as thermodynamics requires the use of activitiesa i . These are in fact concentrations (expressed in moles per liter) multiplied by a certain coefficient called the activity factor (f i ), so that for any species i :

a i = f i ...

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