2. Estimation of critical constants
Two types of methods have been proposed for estimating critical constants: analytical methods and methods based on functional group contributions. All these methods are empirical, i.e. they attempt to find and quantify analogies between them, based on an analysis of experimental data for the same family of compounds.
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Estimation of critical constants
References
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(1) - NELSON (L.C.), OBERT (E.F.) -
Generalized PVT properties of gases
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. Trans. Am. Soc. Mech. Eng. 76, p. 1057-66 (1954).
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(2) - BREEDVELD (G.J.F.), PRAUSNITZ (J.M.) -
Thermodynamic properties of supercritical fluids and their mixtures at very high pressure
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