1. Modeling substance contamination of plastic materials
Thermoplastics, improperly called "plastics" or "plastic materials", are made up of long intertwined chains of polymers (molecular weight greater than 50,000 g · mol
-1
) and formulated with various additives (plasticizers, colorants, stabilizers, etc.) to meet the material's technical specifications. The interlacing of macromolecules is associated with a slow relaxation process at room temperature, responsible for the high cohesive energy of plastics. Polymer chains can locally adopt a crystalline morphology (semi-crystalline polymers) and/or a preferred orientation (oriented polymers). The amorphous phase exhibits two distinct mechanical behaviors, on either side of the glass transition temperature, associated...
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Modeling substance contamination of plastic materials