1. Phase balance
1.1 Review of thermodynamics, phenomenology, and statistics
A heterogeneous system consists of phases separated by interfaces. At equilibrium and in the absence of external forces, the value of any thermodynamic quantity is constant at any point within a phase. At the interfaces, many properties can change more or less abruptly, such as material density, intermolecular interaction energy, entropy, etc., while others, such as chemical potential or temperature, remain constant.
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Phase balance
Crystal forms
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