Suppose we're studying a process of some kind, such as oxidative ageing-induced cross-linking. We determine its maximum speed r at different oxygen pressures p. We then have the curve r = f (p ) in a certain range of p.
Recall that C and p are related by Henry's law:
C = Sp
with :
S
:
depending only on temperature.
Let us now consider all possible hypotheses for the cross-linking mechanism, for example:
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(1) - BOLLAND (J.L.), GEE (G.) -
Trans. Faraday Soc. 42, p. 236-243 et p. 244-252 (1946).
(2) - AUDOUIN (L.), ACHIMSKY (L.), VERDU (J.) -
Kinetic modelling of low temperature oxidation of hydrocarbon polymers.
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Dans Handbook of polymer degradation, 2e éd., édité par...
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