8. Glossary
Metal-Organic Frameworks (MOFs)
Also known as porous coordination polymers, porous hybrid solids composed of organic and inorganic parts linked together by coordination bonds. Due to the nature of these bonds, the construction of these materials gives rise to crystalline networks.
coordination link; coordination bond
An ionocovalent chemical bond in which both electrons in the bond originate from the same atom. Coordination bonds present in MOFs include a metal ion or Lewis acid (electron acceptor), and an atom or ion of an organic molecule or Lewis base (electron donor).
ligand; ligand
In the case of MOFs, a molecule with atoms or ions with chemical functions that can donate electrons to metal ions to form one or more coordination bonds.
topologie; topology
Refers to the geometrical study of the connectivities between the different bricks involved...
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Bibliography
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(1) - LUDI (A.), GUEDEL (H.U.), RUEGG (M.) - Structural chemistry of Prussian blue analogs. Single-crystal study of manganese (II) hexacyanocobaltate (III), Mn3[Co(DcN)6]2.xH2O. - Inorg. Chem., 9, p. 2224-2227 (1970).
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(2) - HOSKINS (B.F.), ROBSON (R.) - Infinite polymeric frameworks...
Also in our database
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CHARPIN (J.), BERNARD (R.) - Mesure des surfaces spécifiques. - [P 1 045] (1982).
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GUISNET (M.), PINARD (L.) - Zéolithes – De la synthèse aux applications. -
Standards and norms
IUPAC (The International Union of Pure and Applied Chemistry): Global standard for chemical nomenclature and terminology.
Regulations
REACH: Regulation (EC) N° 1907/2006 of the parliament and of the council on the Registration, Evaluation, Authorisation and Restriction of Chemicals.
Patents
Process for preparing porous Metal-Organic Frameworks based on aluminum fumarate (2012) US2012/0082864A1
Stable spherical, porous Metal-Organic Frameworks shaped bodies for gas sorption and gas separation (2014) US2014/0213832A1
Directory
Manufacturers – Suppliers – Distributors (non-exhaustive list)
Sigma Aldrich Chimie S.a.r.l
https://www.sigmaaldrich.com/FR/en
Strem Chemicals, Inc.
https://www.strem.com/
BASF SE
https://www.basf.com/fr/fr.html
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