4. Scaling techniques
The growing interest in MOFs in industry goes hand in hand with their production on an industrial scale. This requires a number of parameters to be taken into account, such as the cost of raw materials and the process, safety aspects, toxicity and environmental impact. Ultimately, MOF production must be economically viable, with the final cost having a major impact on the feasibility of industrialization.
On the laboratory scale (from milligrams to a few grams), the aim is first and foremost to obtain the purest product with the best possible crystallinity, in order to study the structure and its fundamental properties. At this stage, little effort is devoted to optimizing the synthesis and/or purification process, and hence to studying the energy impact and/or toxicity of the raw materials. Scaling up is usually the first step in evaluating MOF performance with a laboratory-scale demonstrator,...
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Ongoing reading
Scaling techniques
Bibliography
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(1) - LUDI (A.), GUEDEL (H.U.), RUEGG (M.) - Structural chemistry of Prussian blue analogs. Single-crystal study of manganese (II) hexacyanocobaltate (III), Mn3[Co(DcN)6]2.xH2O. - Inorg. Chem., 9, p. 2224-2227 (1970).
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(2) - HOSKINS (B.F.), ROBSON (R.) - Infinite polymeric frameworks...
Also in our database
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CHARPIN (J.), BERNARD (R.) - Mesure des surfaces spécifiques. - [P 1 045] (1982).
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GUISNET (M.), PINARD (L.) - Zéolithes – De la synthèse aux applications. -
Standards and norms
IUPAC (The International Union of Pure and Applied Chemistry): Global standard for chemical nomenclature and terminology.
Regulations
REACH: Regulation (EC) N° 1907/2006 of the parliament and of the council on the Registration, Evaluation, Authorisation and Restriction of Chemicals.
Patents
Process for preparing porous Metal-Organic Frameworks based on aluminum fumarate (2012) US2012/0082864A1
Stable spherical, porous Metal-Organic Frameworks shaped bodies for gas sorption and gas separation (2014) US2014/0213832A1
Directory
Manufacturers – Suppliers – Distributors (non-exhaustive list)
Sigma Aldrich Chimie S.a.r.l
https://www.sigmaaldrich.com/FR/en
Strem Chemicals, Inc.
https://www.strem.com/
BASF SE
https://www.basf.com/fr/fr.html
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