1. Application of models to nanostructured materials
The essential feature of nanostructured materials is the very
high proportion of the volume that is occupied by grain boundaries,
and more generally by the interfaces, in relation to the volume of
the grains themselves. We have here a crystalline and amorphous phase
mixture. Assuming that the grains are cubic or spherical, we can estimate
the volume fraction of the interfaces at 3
δ/d
,
δ
being
the thickness of the latter and
d
the grain size (this is the
area of the periphery of a grain multiplied by half of the thickness
of the boundaries and divided by the volume of the grain). Assuming
that
...
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Application of models to nanostructured materials