Kinetic modeling of an oxidation mechanism : Initiation by bimolecular decomposition of POOH

Initiation by bimolecular decomposition of POOH
Kinetic modeling of an oxidation mechanism

Authors : Ludmila AUDOUIN, Xavier COLIN, Bruno FAYOLLE, Jacques VERDU

Review date: September 1, 2016 | Lire en français

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3. Initiation by bimolecular decomposition of POOH

We neglect the termination (4) . The mechanistic diagram is therefore : $2 POOH \to P° + {PO}_{2}^{°} (k_{1}$

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Initiation by bimolecular decomposition of POOH

(1) - BOLLAND (J.L.), GEE (G.) - Trans. Faraday Soc. 42, p. 236-243 et p. 244-252 (1946).
(2) - AUDOUIN (L.), ACHIMSKY (L.), VERDU (J.) - Kinetic modelling of low temperature oxidation of hydrocarbon polymers. - Dans Handbook of polymer degradation, 2e éd., édité par...

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