2. Analysis strategy
In all cases of radical oxidation, the oxidation rate rox (rate of oxygen consumption by the substrate), varies with the oxygen concentration C according to a curve whose shape is schematized figure 1.
This is always a curve with a horizontal asymptote rox = rS expressing the fact that the reaction (2) is very fast (typically k2 > 108 L · mol–1· s–1)...
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Analysis strategy
Initiation by bimolecular decomposition of POOH
References
- (1) - BOLLAND (J.L.), GEE (G.) - Trans. Faraday Soc. 42, p. 236-243 et p. 244-252 (1946).
- (2) - AUDOUIN (L.), ACHIMSKY (L.), VERDU (J.) - Kinetic modelling of low temperature oxidation of hydrocarbon polymers. - Dans Handbook of polymer degradation, 2e éd., édité par S.H. Hamid, New York Marcel Dekker, p. 734...
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