2. Fundamental quantities
2.1 Migration time
In capillary electrophoresis, during an analysis, the detector signal is recorded as a function of time to obtain an electrophoregram, like the one shown in figure 5. This makes it possible to determine the exit time at the peak, noted tm for migration time, of each analyte. This is equal to the ratio of the distance covered, which is the effective length of the capillary, i.e. the distance between the sample injection point and the detection point, to the apparent speed...
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Fundamental quantities
Contributions to peak broadening
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