5. Effect of heat treatment on electroless nickel-boron coatings
As expected, electroless nickel-boron coatings without special treatment show a metastable structure that does not correspond to that predicted by the nickel-boron phase diagram for these boron contents. This is because the solubility of boron in nickel at room temperature is extremely low, and numerous intermetallic compounds (such as Ni2B, Ni3B, Ni4B3...) can be formed as a function of the boron content of the mixture . The hardness of these borides, some of which have crystal structures similar to hard phases such as cementite, is high....
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Effect of heat treatment on electroless nickel-boron coatings