1. Theoretical bases and principles of constant flow analysis
History
The term Flow Injection Analysis (FIA) was first used in 1975 by Ruzicka and Hansen
[2]
to designate the operation whereby a sample solution was injected into a moving fluid using a hypodermic syringe; this sample was then drawn towards a detector, a spectrophotometer in the case of a phosphate solution, or a potentiometric detector in the case of an ammonia solution.
An early example of this type of method can be found in the work of Nagy et al.
[3]
, where a mixing chamber placed in the path of a solution injected into a transport electrolyte enabled rapid and complete homogenization of the solution to be analyzed with the electrolyte.
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Theoretical bases and principles of constant flow analysis