Sodium hypochlorite NaClO

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Sodium hypochlorite NaClO

Author : Jean-Christophe MILLET

Publication date: September 10, 2007 | Lire en français

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AUTHOR

  • Jean-Christophe MILLET : Process Manager. Chlorochemistry Division - Arkema

 INTRODUCTION

There are two industrially-developed processes for obtaining sodium hypochlorite:

  • the chemical process which is the main subject of this text;

  • the electrochemical process, in which a sodium chloride solution (brine or seawater) is fed to electrolyzers with or without a separator, generating chlorine at the anode and sodium hydroxide at the cathode. In the case of electrolyzers without separators, hypochlorite is obtained in situ; otherwise, the two reagents are mixed in a specific reactor. This process is characterized by dilute solutions with less than 10 g/l active chlorine.

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