When a quantity of heat ΔQ is received by a system and causes a temperature change ΔT = T1 – T2 (with T1 and T2 , respectively the start and end temperatures of heating), the average heat capacity C of the system of mass m is written :C = ΔQ /ΔT
provided the system undergoes neither reaction nor first-order transition in the Ehrenfest sense (enthalpy and entropy discontinuities) between T1 and T2 , i.e. heat exchanges with the outside have the exclusive effect of raising the temperature of the system (neither heat of reaction nor enthalpy of change of state).
The limiting value of C when ΔT tends towards zero is...
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(1) - TOULOUKIAN (Y.S.), BUYCO (E.H.) - Thermophysical properties of matter, Specific heat : metallic elements and alloys (vol. 4) et Nonmetallic solids - (vol. 5). IFI /Plenum, New York (1970).
(2) - HULTGREN (R.), DESAI (P.D.), HAWKINS (D.T.), GLEISER (M.), KELLEY (K.K.), WAGMANS (D.D.) - Selected values of the thermodynamic...
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