3. Coordination polyhedron

The ability of actinyl oxocations to accept one or more ligands (mono or polydentate) in the equatorial plane (figure 6 a) depends largely on steric and electronic effects. Among these ligands, those with donor oxygen atoms have been extensively studied. Hydroxyl, carbonate and phosphate groups are the main donor groups

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Coordination polyhedron

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References

(1) - MICHALOWICZ (A.) - Logiciels pour la chimie : EXAFS pour le Mac - . Société française de chimie, 116 (1991).
(2) - DEN AUWER (C.), CHARBONNEL (M.C.), MADIC (C.), GUILLAUMONT (R.) - Polyhedron, 17, 4507-4511 (1998).

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