Thermodynamics of polymer solutions
Polymers in solution

Article REF: A3050 V2

Thermodynamics of polymer solutions
Polymers in solution

Authors : Patrick PERRIN, Dominique HOURDET

Publication date: January 10, 1997 | Lire en français

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1. Thermodynamics of polymer solutions

1.1 Concentrated solutions

1.1.1 Flory-Huggins network

1.1.1.1 Concept

Unlike mixtures of small molecules, polymer solutions show a clear deviation from ideality (Raoult's law), the greater the molar mass of the polymer. This unusual behavior...

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References

(1) - FLORY (P.J.) - Principles of Polymer Chemistry. - Cornell University Press, Ithaca, New York (1953).
(2) - FLORY (P.J.) - J. Chem. Phys., 9, p. 660 (1941) ; 10, p. 51 (1942).
(3)...

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