Chromatographic properties of carbon dioxide-based mobile phases
Supercritical Fluid Chromatography

Quizzed article REF: P1460 V4

Chromatographic properties of carbon dioxide-based mobile phases
Supercritical Fluid Chromatography

Author : Didier THIÉBAUT

Publication date: September 10, 2016, Review date: October 1, 2021 | Lire en français

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2. Chromatographic properties of carbon dioxide-based mobile phases

2.1 Thermodynamic aspect

2.1.1 Influence of density

As in CPL, retention depends on solute-stationary phase, solute-supercritical fluid and supercritical fluid-stationary phase interactions. Solute-supercritical CO ₂ interactions can be governed by varying its pressure and, hence, its density (figure 6 )

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Bibliography

(1) - KLESPER (E.), CORWIN (A.H.), TURNER (D.A.) - High pressure gas chromatography above critical temperatures. - J. Org. Chem., 27, p. 700 (1962).
(2) - SMITH (R.M.) - Supercritical chromatography. - Series RSC Chromatography Monographs,...

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