Specific mechanisms and associated measurement techniques
Luminescent materials: techniques of optical and spectroscopic characterization

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E6327 V1 Article

Specific mechanisms and associated measurement techniques
Luminescent materials: techniques of optical and spectroscopic characterization

Author : Richard MONCORGÉ

Review date: April 1, 2025 | Lire en français

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4. Specific mechanisms and associated measurement techniques

4.1 Absorption/excitation spectroscopy of ions in excited states

These are pump-probe techniques in which a particular metastable level is excited, usually with a laser tuned to the excitation wavelength in question, and the absorption (or excitation of higher-energy emitting levels) is probed with a broadband lamp associated with a monochromator, or with a tunable laser. Depending on the wavelength range, the radiative lifetimes of the excited levels and the cross-sections of the optical transitions involved, a set-up using pulsed or continuous-wave light sources is chosen.

  • Pulsed light sources

    The first set-up (figure

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