4. Modeling kinetic constants
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4.1.1 Principle and theoretical approach
When studying the thermal decomposition of a material, in order to establish the reaction scheme to be implemented on a material scale, it is advisable to rely on a decomposition chemistry that is globally understood by the analysis of pyrolysis and decomposition gases, as an approach based solely on the observed mass loss is insufficient to select one of several possible reaction schemes.
To understand the phenomena...
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Modeling kinetic constants
Bibliography
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(1) - KISSINGER (H.E.) -
Reaction kinetics in differential thermal analysis.
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Analytical Chemistry, vol. 29(11), p. 1702-1706 (1957).
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(2) - FRIEDMAN (H.) -
Kinetics of thermal degradation of char forming plastics...
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