The morphology of an emulsion is largely determined by the phase behavior of the same S/H/E system at equilibrium, and therefore by the physico-chemical formulation expressed by the HLD value. Three other parameters are also involved:
the relative proportions of water and oil ;
the concentration of the surfactant and its ability to form liquid crystals;
the experimental protocol used to prepare the emulsion.
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(1) - EVERETT (D.H.) -
Definitions, terminology and symbols in colloid and surface chemistry – Part I, Appendix to manual of symbol and terminology for physicochemical quantities and units
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. Pure Appl. Chem., 31, p. 579-638 (1972).
(2) - EVERETT (D.H.), KOOPAL (L.K.) -
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