4. Catalytic Staudinger reaction
Another major reaction promoted by phosphines is the Staudinger transformation . However, Staudinger reduction must be distinguished from Staudinger ligation (figure 14). Both reactions begin with the formation of an iminophosphorane intermediate, starting from an azide (R-N3). This species possessing a P=N double bond was discovered...
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Catalytic Staudinger reaction
Bibliography
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(1) - VALENTINE (D.H.), HILLHOUSE (J.H.) - Alkyl phosphines as reagents and catalysts in organic synthesis. - Synthesis 3, p. 317 (2003).
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(2) - XU (S.), HE (Z.) - Recent advances in stoichiometric phosphine-mediated organic synthetic reactions. - RSC Advances 3, p....
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