3. Electrolytic pickling
This type of pickling is generally used on stainless steels, which are continuously treated (strip). The principle is simple: the product to be pickled is subjected to anodic and/or cathodic polarization. The objectives are manifold:
accelerated proton penetration of the oxide layer (under the effect of the electric field),
reduction of "higher" oxides (calamines) to iron protoxide,
action of gaseous evolution (oxygen + hydrogen) at the metal interface, resulting from alternating anodic and cathodic polarization, and promoting desquamation of the scale layer,
better control of stripping conditions,
productivity gains
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Electrolytic pickling