Expanded polystyrene (EPS) is a rigid, low-density alveolar material, mainly used for thermal insulation in buildings and for packaging industrial and food products.
There are two types of expanded polystyrene:
EPS-M is obtained from crystal polystyrene to which a blowing agent (pentane, C
5
H
12
) has been added during polymerization.
EPS-E is obtained during extrusion by injecting an expansion gas (pentane) under pressure into the molten crystal polymer.
The most outstanding properties of expanded polystyrene are :
its low density;
thermal insulation ;
excellent mechanical properties (compressive strength, shock absorption);
its insensitivity to water;
its ease of shaping (molding, cutting);
recyclability.
Last but not least, the large-scale production of styrene and the ease with which this monomer can be polymerized make it a particularly attractive property/price compromise for the two main markets for expanded polystyrene.
The discovery of polystyrene dates back to 1839, but it was first used industrially in Germany and the USA in 1933. The first process used (aqueous suspension) was discontinuous.
By the 1940s, both continuous and discontinuous "bulk" polymerization processes were appearing. The "continuous mass" process triumphed in the 1960s, thanks to technological advances enabling the heat produced by polymerization (∼ 710 kJ/kg) to be dissipated.
Expanded polystyrene was invented in 1944 by Ray Mc Intire (1919-1996) while working for Dow Chemical. Discovered by chance, this polystyrene was marketed under the name "Styrofoam". A rigid, low-density material, it was first used as thermal insulation in the building industry.