4. Physico-chemical characteristics
The critical property of carrageenan is its depolymerization by
acid hydrolysis. It has been determined that this effect is linked
to the molecule's anhydrous 3,6 bond. Carrageenans in gel form are
more resistant to acid than those in solution. This is due to the
fact that the secondary and tertiary structures developed during the
gelation phase have a protective effect on gluconic bonds, preventing
them from breaking. This effect enables carrageenan gelling agents
to be used in acidic systems, especially in the presence of potassium
ions (which facilitate gel formation).
Acid hydrolysis proportional to H
3
O
+
ion
activity increases with temperature....
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Physico-chemical characteristics