1. Contamination under thermodynamic control: effect of the partition coefficient
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1.1.1 Microscopic description of thermodynamic equilibrium
Noting the packaging, P, and the food, F, thermodynamic equilibrium corresponds to a situation where the cumulative free energy of P and F, noted G
P+F
, is minimal, and characterizes the state towards which the packaging-food system spontaneously evolves when P and F are placed in contact. It corresponds to thermal, mechanical and chemical equilibrium between the two compartments. At uniform pressure...
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Contamination under thermodynamic control: effect of the partition coefficient
References
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(1) - AZ (R.), DEWALD (B.), SCHNAITTMANN (D.) -
Pigment decomposition in polymers in applications at elevated temperatures.
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Dyes Pigments, 15, p. 1-14 (1991).
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(2) - BANNER (A.L.), PIRINGER (O.G.) -
Prediction of solute partition coefficients between polyolefins...
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