Olefin metathesis
Metathesis: from polymerization to the synthesis of complex molecules
Article REF: AF6232 V1
Olefin metathesis
Metathesis: from polymerization to the synthesis of complex molecules

Authors : Janine COSSY, Claude COMMANDEUR, Malgorzata COMMANDEUR

Publication date: July 10, 2012 | Lire en français

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1. Olefin metathesis

As previously reported, as early as 1971, Y. Chauvin and J.L. Hérisson, , proposed a mechanism involving a metal-carbon that could act as a catalyst in the metathesis reaction between two monosubstituted olefins A and B (figure 1 ). While the steps in this mechanism are reversible, the...

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