4. Substitution with internal rearrangement
Internal rearrangements are a consequence of atoms moving closer together within the coordination sphere, following complexation.
![Representation of the molecule [Mn (CO)4 (CH2CHCH2)] featuring a three-electron-donating allyl ligand.](/en/document/media/content/en/article/af6502/1/af6502i52)
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Substitution with internal rearrangement
Substitution with internal rearrangement
Stabilization of unstable species by complexation
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