Bragg and Williams and Guggenheim models
Statistical thermodynamics - Thermodynamics of solutions
Article REF: AF4061 V1
Bragg and Williams and Guggenheim models
Statistical thermodynamics - Thermodynamics of solutions

Author : Catherine COLINET

Publication date: January 10, 1998 | Lire en français

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1. Bragg and Williams and Guggenheim models

1.1 Basic assumptions

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1.1.1 Configuration partition function

Let's consider the A-B solution as a closed system defined by the independent variables N A , N B , V and T. The canonical set partition function is (cf. equation (13), AF 4,060) :

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