2. Kinetic diagram. Instantaneous" distribution of degrees of polymerization

2.1 Kinetic diagram of radical polymerization in a homogeneous medium

2.1.1 Usual assumptions and approximations

We will restrict ourselves to monomers with a single carbon-carbon double bond reactive in free-radical polymerization. The most general typical kinetic scheme involves seven types of chemical processes: initiation, propagation, depropagation, termination, intermolecular transfers, intramolecular transfer/migration and β-scission (Table 2 ). The...

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Kinetic diagram. Instantaneous" distribution of degrees of polymerization

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Bibliography

(1) - PLADIS (P.), MEIMAROGLOU (D.), KIPARISSIDES, (C.) - Prediction of the viscoelastic behavior of low-density polyethylene produced in high-pressure tubular reactors. - Macromol. React. Eng., 9, p. 271-284 (2015).
(2) - BROOKS (B.W.) - Why are polymerization...

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