Working principle of batteries
Lithium ion batteries - Working mechanism, state-of-the-art and perspectives

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D3354 V2 Article

Working principle of batteries


Lithium ion batteries - Working mechanism, state-of-the-art and perspectives

Authors : Jolanta ŚWIATOWSKA, Domitille GIAUME

Publication date: December 10, 2024 | Lire en français

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1. Working principle of batteries

The working principle of secondary batteries is based on a controlled and reversible reaction occurring between two electrode materials that are separated by an electrolyte. This reaction is an oxidation-reduction reaction, in which the two electrodes exchange charges: negatively-charged electrons flow through an external electrical circuit from one electrode to the other, while positively-charged ions move through the electrolyte inside the battery cell. The direction of charge flow is from the negative electrode to the positive electrode on discharge, and vice versa on recharge.

Nota:

in batteries, while electrodes interchange roles between cathode and anode, conventionally, the positive electrode is referred to as the “cathode” and the negative electrode as the “anode”, based on their discharge functions.

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